Superatoms have being researched because they could replace other elements. Superatom availability has drawn attention to the solution-phase synthesis of superatoms. The preceding method, however, is essentially restricted to the development of a single cluster. Here, superatoms are studied, and the presence of different numbers of gallium atoms is designed to alter the amount of valence electrons in these superatoms. Clusters of 3, 12, 13, and various numbers of atoms have been manufactured using the dendrimer template approach. Ga13 is structurally and electrochemically observed to be entirely distinct from the other clusters due to its halogen-like superatomic composition. The reactivities of the 13 and 3 atom gallium clusters, which may fill the 2P and 1P superatomic orbitals, respectively, vary.